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文章来源:北京大华铭科环保科技有限公司发布者:北京大华铭科环保科技有限公司发布时间:2013-09-26 14:14:13
第12部分 SQU 异味处理技术原理

机构性描述

上海快3SQU SHIZHIGONGZHENLIANGZIXIETONGJISHU,QIHEXINYUANLISHI"JI YUDIGONGLVGUANGYOUFADEFENZIKUAISUFANYING"(Low Dencity Light Induce fast Molecular Reaction)。GAIJISHUYOUSANGEJIBENDANYUANZUCHENG,MEIGEDANYUANBENSHENYIJINGJUYOUXIANGDANGDECHUCHOUYUYANGHUANENGLI,TONGSHI,DANGSANGEDANYUANYIMOUZHONGFANGSHIOUHE,QIEOUHEFANGSHIFUHEGONGZHENTIAOJIANSHI,HUIFASHENGXIETONGZUOYONG,SHIDEXINGNENGXIAOGUODEDAOJIDATIGAO,SHIYANZHENGMINGYIBANKEDEDAOJIWANBEIDAOJISHIWANBEIDEXIAOGUO。

第一单元——增压器技术单元:基于高能电子激发原 理(简称 A 技术)

上海快3GAIJISHUSHIYOUBENGONGSIZHUANYONGDE"SANJIAOMIANFANGDIAN"DIANZIJIFAQI,YUQITA"DBD"BUTONG,BENJISHUJUYOUXIAOLVJIGAO,MUBIAOWUCHANLVDA,SHOUWENSHIDUYINGXIANGXIAODENGTEDIAN。TONGGUOGAONENGDIANZIJIFAQI,CHANSHENGDALIANGHUOXINGJITUAN,YUWURANWUJINXINGFUZADEWULIHUAXUEFANYING,CHANSHENGGAONONGDUDEYINFAJI、YANGHUAJI、CUIMIEJI。ZAIDAODAXIAYIGONGYIZHIQIAN,KEYIXIAOCHUBUFENWURANWU。TONGGUOKUOSANGUOCHENG,DADAOJUNYUNXIANG,JINRUXIAYIGONGYI。YOUYUGAIJISHUDEGUOCHENGGUOFENFUZA,LIRUJIN SO2、NH3 DEFANYINGFANGCHENGJIUYOU 78 GEZHIDUO,ZAIYIPIANWENZHANGZHONGWUFAJINSHU,GULVEJIESHIQIJIBENGUOCHENGRUXIA:

上海快3JIYUCHOUYANGDEYANGHUAJISHUYIJINGSHICHENGSHUDEJISHU,DANSHIYOUYUCHOUYANGDEFENJIESULVJIAODI,SHIJIANCHANGSHUJIAODA,YIBANKEYIDADAO 5 GEXIAOSHI,SUOYIZAIQITICHULIZHONG,WUFAJINXINGYOUXIAODIDONGLIXUESHEJI,YAODADAO 90% DEWURANWUQUCHUXIAOLV,XUYAOJIDADEGONGLV。TONGSHI,YEXUYAOFANYINGQIYOUJIDADETIJI,YIBAOZHENGFANYINGSHIJIAN,ZHEIJIUSHIPUTONGDEDENGLIZITIFANYINGQIJIQIANGGUIDEYUANYIN。

本技术并非以臭氧的简单氧化,或者以臭氧分解产物 - 羟基做单一氧化剂的所谓"高级氧化技术",臭氧及其他产物,仅仅是反应过程的一个参与者,需要进一步的过程才会发挥作用。虽然会有部分氧化作用,理论计算表明,对污染物的去除率在本过程中不会超过 30%。

第二单元——量子激发器技术(简称 B 技术)

上海快3XIANDAIKEXUEYANJIUBIAOMING,QIWEIZAIYOUYUWUZHIDELIANGGETEXINGSUOJUEDING,YIWEIWUZHIDEFENZILIANG,LIRUTANHUANSUITANSHUMUDEZENGJIA,QIQIWEIZHUJIANJIANRUO,DADAO 18 GETANSHI,JIUMEIYOUQIWEILE。ERWEITEDINGDEFENZITUAN,CHENGWEIFACHOUTUAN,LIRUQIANGJIDENG。MOUXIEWUZHILIRU H  2S BENSHENJIUSHIFACHOUTUAN。JIYUCI,RUGUONENGGOUJIANGFACHOUTUANFENJIEHUOZHEDUANKAIYUJIZUODELIANJIE,ZEWUZHISHIQUQIWEI。JIWOMENBUXUYAOFENJIEZHENGGEFENZI,ZHIXUYAOFENJIEFACHOUTUAN。

YOUGENJUWULIXUEDEJIBENCHANGSHI,NENGLIANGCHABIEGUODADELIZIZHIJIANBUHUIJINXINGNENGLIANGCHUANDI,YEJIUSHIBUXISHOU,SUOYIZHENDUIBUTONGWURANWU,XUYAOBUTONGDEBOZHANG。TONGGUODIAOKONGGUANGZINENGLIANG,JIKEGAOXIAODECHUQUWURANFENZI。LIRUZHENDUI CS 2 XUYAO 183nm,SO2XUYAO 207nm,NH3 XUYAO 175nm DENG。DUIYUFACHOUTUAN,YEYOUYIGEZUIYOUBODUAN,WOMENTONGGUODIAOXIAOZIWAIGUANGYUAN,SHIDEDUIFACHOUTUANJUYOUXUANZEXINGXISHOU,JIUKEYIJIANGFACHOUWUZHI"JIFA"。

CHUYUJIFATAIDEWUZHI,JUYOUJIDADEHUAXUEHUOXING,XIANDAI KEXUEBIAOMING,YIFANGMIAN,JIFATAIWUZHIDEDIANZIGUIDAOCHUYUGAO n TAI,

上海快3QIYUANZIBANJINGHENDA(LIRU,QINGYUANZIDEZUIGAO n ZHIKEDA 630,QIBANJINGYIJINGCHAOGUOQITIFENZIDEJIANJU),SUOYIPENGZHUANGGAILVTIGAOHENDA,LINGWAI,FENZIGOUXINGYEHUIFASHENGBIANHUA,TIGAOPENGZHUANGGAILV。DUIYUYANGHUAWUZHIHEBEIYANGHUAWUZHITONGSHISHIJIAJIFA,ZEFASHENGSUOWEIDE"XIETONG"XIAOYING。GEBIEQINGKUANGXIA,YOUKENENGDADAO 106 BEI。ANZHAOWOMENDEFANGAN,FANTUISUANDEDAODEBEISHUWEI 80000 BEI。YOUYUQITIDUIYUGAIBODUANDEXISHOUSHIXUANZEXINGDE,SUOYIJUYOUJIQIANQUANDETEXING,JIZHICHANSHENGWOMENSUOXUYAODEXIAOGUO,MEIYOUFUCHANPINHEFUZUOYONG,SHIZHENZHENG"LVSE"JISHU。GAIGUOCHENGZAIHESHIDECANYUWUBILIXIA,TONGGUOHESHIGONGLVJIFA,JIKEDADAO 99% DEWURANWUQUCHUXIAOLV。

FANYINGBUZHOU:

上海快3QIJIBENGUOCHENGWEILIANFANYING,GAIGUOCHENGZHONGHUAXUEFANYINGRENGRANJI QIFUZA。

DAZHIBAOKUOSANLEIFANYING,JILIANYINFAFANYING、ZIYOUJICHUANDI FANYINGHELIANZHONGZHIFANYING。

LIRU:

第三单元——光反应器技术:光化学原理(简称C技术)

上海快3GAIDANYUANDUIYUWEIFANYINGWUZHI,JINXINGERCIJIFA,KEYIJIANGCHULIXIAOGUODADAO 99.9%。

RUGUOQIANYIDANYUANSHIGAONENGJIFA,ZEGAIDANYUANSHUYUDINENGJIFA,ZHUYAOSHIZHENDUIBUTONGWUZHIDEBODUANXUANZE,MUQIANJISHUXIAWUFAYONGYIZHONGYUANJIANLAISHIXIAN。

上海快3BENDANYUANDELINGYIMUDE,JIUSHIWEIQIFENJIE。YOUYUCHOUYANGSHIGAONENGYANGHUAJI,DUIYUJINDIMIANDAQISHIYOUHAIWUZHI,HUIYINFADUOZHONGLIANSUOFANYING,TONGSHIDUIZHOUWEIFUSHIXINGJIQIANG,DUIRENTIYESHIYOUHAIDE,SUOYI,XUYAOJIANGQIFENJIE,SHIDEPAIQIKONGFUJINCHOUYANGHANLIANGDADAOWEISHENGBIAOZHUN。

另一个还处于保密阶段的技术原理就是电磁搅拌作用,经仔细设计的表面波反应器投射出特定的电磁波。对发臭团及臭氧进行电磁搅拌,极其有利于提高化学反应速度。

动力学描述

YISHANGFENBUMIAOSHUSHEBEIGEBUFENDEGONGNENG,XIAMIANCONGFANYINGDONGLIXUEJIESHIQIGONGZUOGUOCHENG。

第三单元——光反应器技术:光化学原理(简称C技术)

GAIDANYUANDUIYUWEIFANYINGWUZHI,JINXINGERCIJIFA,KEYIJIANGCHULIXIAOGUODADAO 99.9%。

上海快3RUGUOQIANYIDANYUANSHIGAONENGJIFA,ZEGAIDANYUANSHUYUDINENGJIFA,ZHUYAOSHIZHENDUIBUTONGWUZHIDEBODUANXUANZE,MUQIANJISHUXIAWUFAYONGYIZHONGYUANJIANLAISHIXIAN。

BENDANYUANDELINGYIMUDE,JIUSHIWEIQIFENJIE。YOUYUCHOUYANGSHIGAONENGYANGHUAJI,DUIYUJINDIMIANDAQISHIYOUHAIWUZHI,HUIYINFADUOZHONGLIANSUOFANYING,TONGSHIDUIZHOUWEIFUSHIXINGJIQIANG,DUIRENTIYESHIYOUHAIDE,SUOYI,XUYAOJIANGQIFENJIE,SHIDEPAIQIKONGFUJINCHOUYANGHANLIANGDADAOWEISHENGBIAOZHUN。

LINGYIGEHAICHUYUBAOMIJIEDUANDEJISHUYUANLIJIUSHIDIANCIJIAOBANZUOYONG,JINGZIXISHEJIDEBIAOMIANBOFANYINGQITOUSHECHUTEDINGDEDIANCIBO。DUIFACHOUTUANJICHOUYANGJINXINGDIANCIJIAOBAN,JIQIYOULIYUTIGAOHUAXUEFANYINGSUDU。

上海快3DINGYI:CHOUYANGJIQICHANWUYUWURANWUJINXINGHUAXUEFANYING,QIFANYINGSULVWEI v1。DANGSHIYONGMOUZHONGZIWAIXIANFUZHAOWURANWUSHI,QIFANYINGSULVWEI v2。RUGUOJIANGLIANGGEGONGYIJIADAOTONGYIGEFANYINGQIZEFANYINGSULV >(v1+v2),GAIXIANXIANGJIAOZUO"XIETONGXIAOYING"。XIETONGXIAOYINGSUIRANZENGJIALEFANYINGSULV,DANZENGJIABEISHUYOUXIAN。DANGWOMENKONGZHIDUOGEZIWAIXIANDEPINLVJIQIGONGLV,SHIZHIMANZUMOUGEBILI,TONGSHIKONGZHICHOUYANGDENONGDU,ZEZAIQITAYINSUCANYUXIA,HUIYUMOUZHONGFENZIJIEGOULIRU"FACHOUTUAN"CHANSHENGDABEISHUDEXIETONGXIAOGUO。 WOMENCHENGMANZUZHEIZHONGBILIDEDUOZHONGZIWAIXIANFUHE"GONGZHENTIAOJIAN"。YOUYUDUOZHONGZIWAIXIANBAOKUOLEYUANZIWAIYUZHENKONGZIWAIZAINEIDESHIJIGEBODUAN,SUOYITONGCHENGWEI"GUANGLIANGZI"。YINGYONGYISHANGYUANLIKAIFADEFEIQICHULIJISHUBEICHENGWEI"GONGZHENGUANGLIANGZIYUCHOUYANGJICHANWUXIETONGXIAOYING"JISHU,JIANCHENG"GONGZHENLIANGZIXIETONG"JISHU。

QIJIBENYUANLIZAIYUGUANGHUAXUEJISHUZHONGDEGONGZHENJIFA、LIANFANYING、CHOUYANGYANGHUAJIGAOJIYANGHUADENG。YIXIAFENXUZHI:

上海快3SHOUXIANSHICHOUYANGYANGHUA,YIYOU 100 NIANDEYINGYONGLISHILE,DANSHIZUIJINYOUYUCHOUYANGFASHENGQIJISHUDETUPOXINGJINZHANCAIDEDAOGUANGFANYINGYONG,QIYUANLIYEYIJINGDEDAOCHANSHU。QIHOUXUCHANWULIRUQIANGJIDEYANGHUAXINGYEDEDAOCHONGFENYANJIU,BEICHENGWEIGAOJIYANGHUAJISHU。YOUYUQIJINCIYUFUDEYANGHUADIANWEI,SUOYIGUANGFANYINGYONGYUSHUIDECHULIHEFEIQIDECHULIZHONG。

上海快3GUANGLIANGZIDEZUOYONGMUQIANYANJIUDEBINGBUCHONGFEN,DUI"XIETONGXIAOYING"DEJILIYANJIUYEWUZHONGDAJINZHAN。CHULIYONG 185nm BODUANCHANSHENGDINONGDUCHOUYANGWAI,SIHUWUQITAYINGYONG,TEBIESHIDIQIANGDUDEZIWAIGUANG,HENSHAODANDUYONGYUHUAXUEFANYING,ZHEIYUZIWAIJIGUANGDEQINGXINGQIAHAOXIANGFAN,JUEDADUOSHUDEYANJIUCHENGGUODOUSHI"WEIXIANG"DE。

"GONGZHENLIANGZIXIETONG"JISHUDEJILIYANJIUYUCILEISI,DANYIXIAJIDIANSHIYIJINGBEIZHENGSHILEDE。

1.JIFATAIYUANZIDEFANYINGJIEMIANZENGJIA。LIRU,CHUYULIBODETAIDELEIQINGYUANZI,QIGUIDAOBANJINGYU n2 CHENGZHENGBI。TONGSHICHUYULIBODETAIDEDIANZIJIHUMEIYOUCHUANTOUZUOYONG,YUZIYOUDIANZILEISI,SUOYIQIPENGZHUANGJIEMIANJIDA,HUAXUEFANYINGHUOXINGJIGAO。

2.BEIJIFADEFENZI,QIGOUXINGHUIFASHENGBIANHUA,ZENGJIALEFANYINGJIEMIAN。

3.CHOUYANGXISHOUMOUZHONGZIWAI(254nm)HOUHUIFENJIE,DANQIFENJIESULVYOUYULINGYIZHONGZIWAIXIANYOUGUAN。SHIYANFAXIANYOUYIGEZUIYOUZHICUNZAI。ZAICIZUIYOUZHUANGTAIXIA,CHOUYANGJUYOUZUIDAHUAXUEHUOXINGHEZUIGAODONGLIXUECHANGSHU。

4.WURANWUDEMOUXIEJIEGOUDUIYINGYIGEZUIYOUXISHOUTIAOJIAN,CHENGWEIGONGZHENXISHOU。LIRU:ZHENDUI CS2 XUYAO 183nm,SO2 XUYAO 207nm,NH3 XUYAO 175nm DENG。KONGZHIGUANGLIANGZIDENENGLIJIUKEYISHIDEWURANWUBEIZUIDAJIFA。

5.  LIANFANYINGXUYAOYINFA、CUIMIE、GUOQIAODENGDUOZHONGFUZHUJIXING,HELIKONGZHIFUZHUJIXINGXIANRANKEYIZENGJIAFANYINGSULV。

上海快36.   YISHANGJIZHONGQINGKUANGXIA,MEIYIZHONGDEZENGYICHANGSHUSHEWEI Ai,ZEZONGHEZENGYIWEI A=∏Ai。

XIANRAN,CHENGFAXINGZHIDEZENGYI,JUYOUHENDADESHUZHI。YIBANJIANDANDEKONGZHIJIUNENGHUODEJINQIANBEIDEZENGYI,GAOXIAODEKONGZHIHUIDEDAOJISHIWANBEIDEZENGYI。YIBANCHOUYANGDEBANSHUAIQIWEI 16 XIAOSHI,10 WANBEIDEZENGYIYIWEIZHEMIAOJISHIJIAN,ZHEIJIUSHIKEYIZAIMIAOJISHIJIANNEICHULIWURANWUDEDONGLIXUEYUANLI。

CONGFENZIPENGZHUANGJIEMIANDEGOUCHENGLAIKAN,RUODINGYI S WEIPENGZHUANGJIEMIAN,ZE:

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QIZHONG:

上海快3k:DONGLIXUEXISHU,DUIYUGUDINGDEFANYING,WEICHANGSHU

上海快3r:FENZIJIHEJIEMIAN,QUJUEYUZUIWAICENGJIADIANZIDEZHULIANGZISHU,YIJIFENZIDEGOUXING。

n:FANYINGFENZIMIDU。

l:ZIYOUCHENG,QUJUEYUQITIYALI、WENDU、MIDUDENGTIAOJIAN。

上海快3CONGBENGONGYIDEZUOYONGLAIKAN,DIYIDANYUANZENGJIALE n1 DEZHI;DIERDANYUANZENGJIALE r DEZHI,JIANSHAOLE l DEZHI。YOUYUGONGSHIZHONGWANQUANSHICHENGFAGUANXI,SUOYIQIPENGZHUANGJIEMIANSHIYICHENGFADEZHIBIAOZENGJIA,TEBIESHI l,JINYULINGSHIJIEMIANWUXIANZENGDA,JIWUXUPENGZHUANG,ZHIJIEJIECHU。

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上海快3DIERHEDISANDANYUANDOUZENGJIALE P DEZHI,JIANSHAOLE t DEZHI,SUOYIKEYIXIANZHUTIGAOFANYINGSULV。

FANYINGSULVDEZENGJIA,SHIJISHANGDUIYUFANYINGDONGLIXUEERYAN,KEYIJIANXIAOXITONGTIJI,JIANGDIXITONGZULI,XIANRANJIUNENGJIANGDINENGHAO,TIGAOCHULIXIAOLV。

上海快3WOMENZHIDAO,BUTONGDEDIANCIBODUANDUIYUFENZIERYAN,JUYOUBUYONGDEZUOYONG。LIRUHONGWAIDUIYUFENZIJUYOUZHENDONGZUOYONG,WEIBODUANDUIYUFENZIJUYOUZHUANDONGZUOYONG,GAOSUZHUANDONGDEJIXINGFENZIQIPENGZHUANGJIEMIANHEFANYINGSULVDOUHUIYOUHENDADETIGAO,SUOYITONGGUOJIFAQIDEDUOBODUANTEZHENG,KEYIYOUXIAODEZENGJIAFANYINGJIEMIANHEFANYINGSULV。

工程应用

YIBANHUAXUEFANYINGFENWEIQI - QIFANYING,QI - YEFANYING,QI - GUFANYING。

上海快3XIANRAN,FANYINGSUDUDANGSHUQI - QIFANYINGZUIKUAI,QI - YEFANYINGCIZHI,ERQI - GUFANYINGZUIMAN。YUANYINZAIYUQI - QIFANYINGSHIZHIJIEQUJUEYUPENGZHUANGJIEMIAN,SHIZHENGBIGUANXI。ERQI - YEFANYINGXUYAOCHUANZHI,DANYETINEIBUZESHIGAOPENGZHUANGDE,SUOYISUIRANXIAOYUQI - QIFANYING,DANDAYUQI - GUFANYING。QI - GUFANYINGJUXIANYUGUTI BIAOMIAN,YINCIFANYINGSUDUZUIMAN。

JIYUCI,BENJISHUDESUOYOUYANGHUAJIDOUSHIQITAI,YINCIJIAOZHIXIFUFA、XISHOUFA、SHENGWUFADENG,QIFANYINGSUDUXIANRANBUZAIYIGESHULIANGJI。

上海快3SHOUXIANSHIFENGJIGONGHAO,YOUYUWUXUCHUANZHI,SUOYIZULIJIXIAO。

上海快3QICIWUXUTIANJIAYAOJI,SUOYIYUNXINGCHENGBENJINWEIDIANFEI。

ZUIHOUYOUYUFANYINGSULVJIGAO,YINCIZHUANGZHITIJIJIAOXIAO,ZAOJIAJIAODI。

GUANYUXUANZEXINGWENTI:

实验表明,共振量子协同技术对于"发臭团"似乎具有特殊的亲和性,其反应速率与臭氧与污染物的反应顺序似乎并不吻合。理论上,臭氧应该按照"链烯烃>胺>酚>多环芳香烃>醇>醛>链烷烃"的顺序发生反应,但是在共振量子协同技术中,化学反应顺序是按照"官能团"被激发的难易程度反应的。这可能是由于臭氧反应首先会采取亲电反应的方式,所以首先与"官能团—例如发臭团"发生反应,而很少与苯等发生加成反应。已经发现如下事实:共振量子协同技术处理气味分子更加有效,比处理其他废气有更快的速度。

GUANYUYANGHUASHENDUWENTI:

最简单的"发臭团"靶向氧化需要较小的功率,但对于有毒有害"基团"的氧化需要较大的功率。如果需要对整个有机分子完全氧化成二氧化碳和水,是不经济的。较大的功率不仅无助于"更洁净"的效果,而且由于将大分子攻击成碎片,会引发一系列不可控的中间体。特别的,对于苯系物,一般的氧化产物是苯甲酸,而不是二氧化碳和水。重要的是,对于痕量物质的氧化,其化学反应动力学常数肯定很小,如果要求完全氧化,则需要极其庞大的反应器,这在工程上难以实现。

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